Urine Without Preservative:
Refrigerated (preferred) - 6 days
Ambient - 2 days
Frozen - 6 months
 
Urine With Preservative: 
Refrigerated (preferred) - 8 days
Ambient - 3 days
Frozen - 3 weeks
 
Blood:
Refrigerated (preferred) - 7 days
Ambient - 7 days
Frozen - 3 months